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These aggregations have different consequences in the solid state structures. Crystals of [Pt 2 L 4 ] show electrical behaviour characteristic of semiconductors. Furthermore, partial oxidation of [Pt 2 L 4 ] with iodine generates supramolecular 1D assemblies of formula [Pt 2 L 4 I] n based on week metal-ligand interactions. Assembly and disassembly of [Pt 2 L 4 I] n conductive structures, even at the nanoscale, allows to envisage future technological applications in molecular electronics.
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